Синтез, строение и свойства поликатионных клатратов на основе олова и германия — перспективных термоэлектриков
Диссертация
Нами синтезирован твердый раствор 8п24Р19. з18-хВгх неограниченной протяженности со структурой клатрата-1. Определена зависимость параметра, а кубической элементарной ячейки твердого раствора 8п24Р19з18-хВгх от степени замещения йода на бром. Установлены кристаллические структуры 6 составов твердого раствора Бг^Р^.з^хВгх с х = 0, 2.35- 3.14- 4.62- 6.1- 8. Показано предпочтительное заполнение… Читать ещё >
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