Селективные методы пероксидирования ?-дикарбонильных соединений и их гетероаналогов
Диссертация
Впервые осуществлено селективное окисление а-замещенных производных малонодинитрила и циануксусного эфира в а-положение с образованием несимметричных а-тре/и-бутилпероксипроизводных. Обнаружено, что переходные металлы (Си, Fe, Мп, Со) катализируют пероксидирование а-замещеных производных малонодинитрила и циануксусного эфира итре/и-бутилгидропероксидом в а-положение. Метод пригоден для синтеза… Читать ещё >
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