Исследование путей повышения емкости отрицательных электродов литий-ионных аккумуляторов
Диссертация
В условиях работы литий-ионного аккумулятора исследованы электрохимические характеристики отрицательных электродов, изготовленных из графита, модифицированного окислением в озоно-кислородной среде. Установлено, что окисление графита в Оз/С>2-газовой смеси, содержащей 5% Оз, с последующей обработкой e/wo/7-бутиллитием позволяет резко уменьшить необратимую емкость и стабилизировать разрядные… Читать ещё >
Список литературы
- Химические источники тока: Справочник / Под редакцией Н. В. Коровина, A.M. Скундина. М.: Издательство МЭИ, 2003. — 740с., ил.
- Di Pietro В., Patvianca М., Scrosati В. On the use of rocking chair configurations for cyclable lithium organic electrolyte batteries // J. Power Sources. 1982. — V.8. — P.289−299.
- Auborn J J., Barberio Y.L. Lithium intercalation cells without metallic lithium Mo02/LiCo02 and Wo2/LiCo02 // J. Electrochemical Society. 1987. -V. 134. -P.63 8−644.
- Megahed S., Ebner W. Lithium-ion battery for electronic applications // J. Power Sources. 1995. — V.54. — P.155−162.
- Dey A.N. Electrochemical Alloying of Lithium in Organic Electrolytes // J.E.S. 1971. — V.118. — P.1547−1549.
- Jow T.R., Liang C.C. Lithium-aluminum electrodes at ambient temperatures // J. Electrochemical Society. 1982. — V.129. — P.1429−1433.
- Armstrong R.D., Brown O.R., Ram R.P., Turk C.D. Lithium electrodes based upon aluminium and alloy substrates I. Impedance measurements on aluminium // J. Power Sources. 1989. — V.28. — P.259−267.
- Rao B.M.L., Francis R.W., Christopher H.A. Lithium-Aluminum Electrode // J. Electrochemical Society. 1977. — V.124. — P.1490−1492.
- Besenhard J.O. Cycling behaviour and corrosion of Li-Al electrodes in organic electrolytes//J. Electroanal. Chem. 1978. — V.94. — P.77−81.
- Epelboin I., Froment M., Garreau M., Thevenin J., Warin D. Behavior of Secondary Lithium and Aluminum-Lithium Electrodes in Propylene Carbonate // J. Electrochemical Society. 1980. — V.127. — P.2100−2104.
- Geromov Y., Zlatilova P., Staikov G. The secondary lithium— aluminium electrode at room temperature: II. Kinetics of the electrochemical formation of the lithium—aluminium alloy // J. Power Sources. 1984. — V.12. -P.155−165.
- Maskell W.C., Owen J.R. Cycling behavior of thin film lial electrodes with liquid and solid electrolytes // J. Electrochemical Society. 1985. — V.132. -P.1602−1608.
- Besenhard J.O., Hess M., Komenda P. Dimensionally stable Li-alloy electrodes for secondary batteries // Solid State Ionics. 1990. — V.40−41. — P.525−529.
- Химические источники тока с литиевым электродом / И. А. Кедринский, В. Е. Дмитренко, Ю. М. Поваров, И. И. Грудянов. Красноярск: КГУ. — 1983. — 247с.
- Baranski A.S., Fawcett W.R. The formation of lithium-aluminum alloys at an aluminum electrode in propylene carbonate // J. Electrochemical Society. -1982. V.129. — P.901−907.
- Sanchez P., Belin С., Crepy C., De Guibert A. Electrochemical studies of lithium-boron alloys in non-aqueous media-comparison with pure lithium // J. Appl. Electrochem. 1989. — V.19. — P.421−428.
- Besenhard J.O., Komenda P., Paxines A., Wudy E., Josewics M. Binary and ternary Li-alloys as anode materials in rechargeable organic electrolyte Li-batteries // Solid State Ionics. 1986. — V. 18−19. — P.823−827.
- Maxfield M., Jow T.R., Gould S., Sewchok M.G., Shocklette L.W. Composite electrodes containing conducting polymers and li alloys // J. Electrochemical Society. 1988. — V.135. — P.299−305.
- M.Maxfield, J.R.Jow, M.G.Semshok, L.W.Shacklette. Alloy/conducting-polymer composite electrodes: electrolytes, cathodes, and morphology // J. Power Sources. 1989. — V.26. — P.93−102.
- Скундин A.M., Ефимов О. Н., Ярмоленко О. В. Современное состояние и перспективы развития исследований литиевых аккумуляторов // Успехи химии.- 2002.- Т.71.- С. З78−398.
- Scrosati В. Lithium Rocking Chair Batteries: An Old Concept? // J. Electrochemical Society. 1992. — V.139. — P.2776−2781.
- Bittihn R., Herr R., Hoge D. The SWING system, a nonaqueous rechargeable carbon/metal oxide cell // J. Power Sources. 1993. — V.43. — P.223−231.
- Semkow K.W., Sammels A.F. Secondary solid-state spe cells // J. Electrochemical Society. 1987. — V.134. — P.766 -771.
- Herold A.//Bull. Soc. Fr. 1995. V. 187, P. 999. (цитируется no 21.)
- Brandt K. Historical development of secondary lithium batteries // Solid State Ionics. 1994. — V.69. — P.173−183.
- Brener A. Note on an Organic-Electrolyte Cell with a High Voltage //J.Electrochemical Society. 1971. — V.118. — P.461−462.
- Dey A.N., Sullivan B.P. The Electrochemical Decomposition of Propylene Carbonate on Graphite // J. Electrochemical Society. 1970. — V.117. -P.222−224.
- Arakawa M., Yamaki J. I. The cathodic decomposition of propylene carbonate in lithium batteries // J. Electroanalytical Chemistry. 1987. — V.219. -P.273−280.
- Yoshino A., Sanechica K., Nakajima Т.//Патент США № 4.668.595. (цитируется по 21.)
- Mohri М., Vanagisawa N., Tajima Y., Tanaka H., Mitate Т., Nakajima S., Yoshida M., Yoshimoto Y., Suzuki Т., Wada H. Rechargeable lithium battery based on pyrolytic carbon as a negative electrode // J. Power Sources. 1989. -V.26. — P.545−551.
- Inada K., Ikeda D., Sato Y.//Proc. Symp. Electrochem. Soc. 1988. 88−6, P. 530. (цитируется no 21.)
- Nagaura Т. Secondary battery // J. Power Sources. 1996. -V.63.1. P.293.
- Nagaura T. Electrode Materials for Lithium Ion Rechargeable Batteries //Fifth International Seminar on Lithium Battery Technology and applications. March 4−6. 1991. — Deerfield, Florida. — P.255−262.
- Megahed S., Scrosati B. Lithium-ion rechargeable batteries // J. Power Sources. 1994. — V.51. — P.79−104.
- Scrosati В .//Nature. 1995. V. 373, P. 557.(цитируется no 21.)
- Abraham K.M. Directions in secondary lithium battery research and development//Electrochim. Acta. 1993. — V.38. — P.1233−1248.
- Багоцкий B.C., Скундин А.М.Юлектрохимия. 1995. — T.31. — C.342.
- Winter M., Besenhard J.O. Lithiated carbon, in: J.O.Besenhard (Ed.), Handbook of Battery Materials, Weinheim, Wiley-VCH. 1999. — P.383.
- Noel M., Santhanam R. Electrochemistry of graphite intercalation compounds // J. Power Sources. 1998. — V.72. — P.53−65.
- U. von Sacken, Nodwell E., Sundher A., Dahn J.R. Comparative thermal stability of carbon intercalation anodes and lithium metal anodes for rechargeable lithium batteries // Solid State Ionics. 1994. — V.69. — P.284−290.
- Winans R.E., Carrado K.A. Novel forms of carbon as potential anodesfor lithium batteries // J. Power Sources. 1995. — V.54. — P. 11−15.
- Y.P.Wu, E. Rahm, R.Holze. Carbon anode materials for lithium ion batteries // J. Power Sources. 2003. — V. l 14. — P.228−236.
- Sawai K., Iwakoshi Y., Ohzuku T. Carbon materials for lithium-ion (shuttlecock) cells // Solid State Ionics. 1994. — V.69. — P.273−283.
- Ozawa K. Lithium-ion rechargeable batteries with LiCo02 and carbon electrodes: the LiCo02/C system // Solid State Ionics. 1994. — V.69. — P.212−221.
- Wilson A.M., Reimers J.N., Fuller E.W., Dahn J.R. Lithium insertion in pyrolyzed siloxane polymers // Solid State Ionics. 1994. — V.74. — P.249−254.
- Matsumura Y., Wang S., Kasuh Т., Maeda T. The dependence of reversible capacity of lithium ion rechargeable batteries on the crystal structure of carbon electrodes // Synthetic Metals. 1995. — V.71. — P.1755−1756.
- Sandi G., Winans R.E., Carrado K.A. New Carbon Electrodes for Secondary Lithium Batteries // J. Electrochemical Society. 1996. — V. 143. — P.95−98.
- Tokumitsu K., Mabuchi A., Fujimoto H., Kasuh T. Charge/discharge characteristics of synthetic carbon anode for lithium secondary battery // J. Power Sources. 1995. — V.54. — P.444−447.
- George Ting-Kuo Fey, Chung-Lai Chen. High-capacity carbons for lithium-ion batteries prepared from rice husk // J. of Power Sources. 2001. -V.97−98. — P.47−51.
- Барсуков B.3., Ильин E.A., Яскула M. Новые активные материалы для отрицательных электродов литий-ионных аккумуляторов// Электрохимическая энергетика. 2002. — Т.2. — С. 153−164.
- Satoh A., Takami N., Ohsaki Т. Electrochemical intercalation of lithium into graphitized carbons // Solid State Ionics. 1995. — V.80. — P.291−298.
- Li G., Lu Z., Huang В., Huang H., Xue R., Chen L. An evaluation of lithium intercalation capacity into carbon by XRD parameters // Solid State Ionics. 1995.-V.81.-P.15−18.
- Wang S., Matsumura Y., Maeda T. A model of the interactions between disordered carbon and lithium // Synthetic Metals. 1995. — V.71. — P. 1759−1760.
- Tijima Т., Suzuki K., Matsuda Y.//Denki Kagaku. 1993. V. 61, p. 1383.
- Noel M., Suryanarayanan V. Role of carbon host lattices in Li-ion intercalation/de-intercalation processes // J. of Power Sources. 2002. — V.lll. -P.l 93−209.
- Kanno R., Kawamoto Y., TakedaY., Oshashi S., Imanishi N., Yamamoto O. Carbon Fiber as a Negative Electrode in Lithium Secondary Cells // J. Electrochemical Society. 1992. — V.139. — P.3397−3404.
- Kikuchi M., Ikezawa Y., Takamura T. Surface modification of pitch-based carbon fibre for the improvement of electrochemical lithium intercalation // J. Electroanalytical chemistry.- 1995. V.396. — P.451−455.
- Shu Z.X., McMillan R.S., Murray J.J. Electrochemical Intercalation of Lithium into Graphite // J. Electrochemical Society. 1993. — V.140. — P.922−928.
- Kanamura K., Tamura H., Shiraishi S., Takehara Z. Morphology and chemical compositions of surface films of lithium deposited on a Ni substrate in nonaqueous electrolytes // J. Electroanalytical chemistry. 1995. — V.394. — P.49−62.
- Peled E. The Electrochemical Behavior of Alkali and Alkoline Earth Metals in Nonagueous Battery Sistems The Solid Electrolyte Interphase Model // J. Electrochemical Society. — 1979. — V.126. — P.2047−2052.
- Aurbach D., Ein-Ely Y., Zaban A. The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions // J. Electrochemical Society. 1994. -V.141.-P.l-4.
- Kanamura K., Tamura H., Takehara Z. XPS analysis of a lithium surface immersed in propylene carbonate solution containing various salts // J. Electroanalytical chemistry. 1992. — V.333. — P. 127−142.
- Fujieda Т., Yamamoto N., Saito K., Ishibashi Т., Honjo M., Koike S., Wakabayashi N., Higuchi S. Surface of lithium electrodes prepared in Ar + CO2 gas // J. Power Sources. 1994. — V.52. — P. l97−200.
- Odziemkowski M., Irish D.E. An Electrochemical Study of the Reactivity at Lithium Electrolyte/Bare Lithium Metal Interface. II. Unpurified Solvents //J.Electrochemical Society. 1993. — V.140. — P.1546−1556.
- Tudela Ribes A., Beaunier P., Willmann P., Limordant D. Correlation between cycling efficiency and surface morphology of electrodeposited lithium. Effect of fluorinated surface active additives // J. Power Sources. 1996. — V.58. -P.l 89−195.
- Aurbach D., Ein-Eli Y., Chusid O., Carmeli Y., Babai M. Electrochemical and spectroscopic studies of carbon electrodes in lithium battery electrolyte systems // J. Power Sources. 1993. — V.43. — P.47−64.
- Chusid O., Ein-Ely Y., Aurbach D., Babai M., Carmeli V.//Extended Abstracts, 16th International Meeting on Lithium Battareis, Munster, Germany. -1992. P. 16. (цитируется no 21.)
- Besenhard J.O., Winter M., Yang J., Biberacher W. Filming mechanism of lithium-carbon anodes in organic and inorganic electrolytes // J. Power Sources. 1995.-V.54.-P.228−231.
- Lampe-Onnerud C., Shi J., Onnerud P., Chamberlain R., Barnett B. Benchmark study on high performing carbon anode materials // J. of Power Sources. 2001. — V.97−98. — P.133−136.
- Dolle M., Grugeon S., Beaudoin В., Dupont L., Tarascon J-M. In situ ТЕМ study of the interface carbon/electrolyte // J. of Power Sources. 2001. -V.97−98.-P. 104−106.
- Edstrom K., Andersson A.M., Bishop A., Fransson L., Lindgren J., Hussenius A. Carbon electrode morphology and thermal stability of the passivation layer// J. of Power Sources. 2001. — V.97−98. — P.87−91.
- Zane D., Antonini A., Pasquali M. A Morphological study of SEI film on graphite electrodes // J. of Power Sources. 2001. — V.97−98. — P.146−150.
- Zempachi Ogumi, Atsushi Sano, Minoru Inaba, Takeshi Abe Pyrolysis/gas chromatography/mass spectroscopy analysis of the surface film formed on graphite negative electrode // J. of Power Sources. 2001. — V.97−98. -P.156−158.
- Ken-ichi Morigaki. In situ analysis of the interfacial reactions between MCMB electrode and organic electrolyte solutions // J. of Power Sources. 2002. -V.103. — P.253−264.
- Liebenon C., Wagner M.W., Luhder K., Lobitz P. Besenhard J.O. Electrochemical behaviour of coated lithium-carbon electrodes // J. Power Sources. 1995.-V.54.-P.369−372.
- Fujimoto H., Mabuchi A., Tokumitsu К., T. Kasuh. Irreversible capacity of lithium secondary battery using meso-carbon micro beads as anode material // J. Power Sources. 1995. — V.54. — P.440- 443.
- Fong R., von Sacken U., Dahn J.R. Studies of Lithium Interclation Into Carbons Using Non-Aqueous Electrochemical Cells // J. Electrochem. Soc. 1990. -V.137.-P.2009−2014.
- Simon В., Boeuve J. P., Broussely M. Electrochemical study of the passivating layer on lithium intercalated carbon electrodes in nonaqueous solvents // J. Power Sources. 1993. — V.43−44. — P.65−74.
- Chusid О., Ein-Ely Y., Aurbach D., Babai M., Carmeli Y. Electrochemical and spectroscopic studies of carbon electrodes in lithium battery electrolyte systems // J. Power Sources. 1993. — V.43−44. — P.47−64.
- Peled E., Menachem C., Bar-Tow D., A. Melman Improved Graphite Anode for Lithium Ion Batteries Chemically Bonded SEI and Nanochannel Formation // J. Electrochem. Soc. 1996. — V. 143. — P.4−7.
- Menachem C., Peled E., Burstein L., Rosenberg Y. Characterization of modified NG7 graphite as an improved anode for lithium-ion batteries // J. Power Sources. 1997. — V.68. — P.277−282.
- Ohzuku Т., Iwakoshi Y., Sawai K. Formation of Lithium-Graphite Intercalation Compounds in Nonaqueous Electrolytes and Their Application as a Negative Electrode for a Lithium Ion (Shuttlecock) Cell // J. Electrochem. Soc. -1993.-V.140.-P.2490 -2498.
- Billaud D., Henry F. X., Willman P. Electrochemical synthesis of binary graphite-lithium intercalation compounds // Mater. Res. Bull. 1993. — V.28. -P.477−483.
- Nakamura H., Komatsu H., Yoshio M., Fultz B. Suppression of electrochemical decomposition of propylene carbonate at a graphite anode in lithium-ion cells // J. Power Sources. 1996. — V.62. — P.219−222.
- Blomgren G.E. Electrolytes for advanced batteries // J. Power Sources. -1999.-V.81−82.-P.112−118.
- Wu Y.P.,.Wan С, Jiang С., Fang S.B., Jiang Y.Y. Mechanism of lithium storage in low temperature carbon // Carbon. 1999. — V.37. — P. 1901−1908.
- Wu Y.P., Jiang C, Wan C., Holze R. Anode materials for lithium ion batteries by oxidative treatment of common natural graphite // Solid State Ionics. -2003.-V.156.-P.283−290.
- Menachem C., Y. Wang, J. Flowers, Peled E., Greenbaum S.G. Characterization of lithiated natural graphite before and after mild oxidation // J. Power Sources. 1998. — V.76. — P.180−185.
- Buqa H., Golob P., Winter M., Besenhard J.O. Modified carbons for improved anodes in lithium ion cells // J. Power Sources. 2001. — V.97−98. -P.122−125.
- Wang H., Yoshio M. Effect of iodine treatment on the electrochemical performance of natural graphite as an anode material for lithium-ion batteries // J. Power Sources. 2001.- V.101.- P.35−41.
- Aurbach D., Markovsky В., Nimberger A., Levi E., Gofer Y. Electrochemical Li-Insertion Processes into Carbons Produced by Milling Graphitic Powders: The Impact of the Carbon’s Surface Chemistry // J. Electrochem. Soc. 2002. — V.149. — P. 152−162.
- Kim S., Yoon W.-Y., Kwang Soo Yoo, Park G.-S., Lee C.W., Murakami Y., Shindo D. Charge-discharge properties of surface-modified carbon by resin coating in Li-ion battery // J. of Power Sources. 2002. — V.104. — P. 175 180.
- Tran T.D., Feikert J.H., Song X., Kinoshita K. Commercial Carbonaceous Materials as Lithium Intercalation Anodes // J. Electrochem. Soc. -1995.-V.142.-P.3297−3303.
- Zaghib K., Nadeau G., Kinoshita K. Effect of Graphite Particle Size on Irreversible Capacity Loss // J. Electrochem. Soc. 2000. — V.147. — P.2110−2116.
- Novak P., Jono F., Lanz M., Rykart В., Panitz J-Ch., Alliata D., Kotz R., Haas O. The complex electrochemistry of graphite electrodes in lithium-ion batteries // J. Power Sources. 2001. — V.97−98. — P.39−46.
- Jono F., Rykart В., Blome A., Novak P., Wilhelm H., Spahr M. Relation between surface properties, pore structure and first-cycle charge loss of graphite as negative electrode in lithium-ion batteries // J. Power Sources. 2001. -V.97−98. — P.78−82.
- Winter M., Novak P., Monnier A. Graphites for Lithium-Ion Cells: The Correlation of the First-Cycle Charge Loss with the Brunauer-Emmett-Teller Surface Area // J. Electrochem. Soc. 1998. — V.145. — P.428 -436.
- Chung G.-C., Jun S.-H., Lee K.-Y., Kim M.-H. Effect of surface structure on the irreversible capacity of various graphitic carbon electrodes // J. Electrochem. Soc. -1999. V.146. — P.1664−1672.
- Bar-Tow D., Peled E., Burstein L. A study of highly oriented pyrolytic graphite as a model for graphite anode in Li-ion batteries // J. Electrochem. Soc. 1999. — V.146. — P.824−833.
- Zaghib K., Nadeau G., Kinoshita K. Influence of edge and basal plane sites on the electrochemical behavior of flake-like natural graphite for Li-ion batteries//J. Power Sources. 2001.- V.97−98. — P.97−103.
- Aurbach D., Teller H. Morphology/behavior relationship in reversible electrochemical lithium insertion into graphitic materials // J. Electrochem. Soc. -2002. V.149. — P. A1255-A1267.
- Zaghib K., Brochu F., Guerfi A., Kinoshita K. Effect of particle size on lithium intercalation rates in natural graphite // J. Power Sources. 2001. — V.108. -P.140−146.
- Yu P., Popov B.N., Ritter J. A., White R. E. Determination of the lithium-ion diffusion coefficient in graphite //J. Electrochem. Soc. 1999. — V.146. — P.8−15.
- Morita M., Nishimura N., Matsuda Y. Charge/discharge cycling behavior of pitch-based carbon fiber in organic electrolyte solutions // Electrochim.Acta. 1993. — V.38. — P.1721−1726.
- Ein-Eli Y., Koch V. Chemical Oxidation: A Route to Enhanced Capacity in Li-Ion Graphite Anodes // J. Electrochem. Soc. 1997. — V.144. -P.2968−2973.
- Nakajima J., Gupta V., Ohzawa Y., Iwata H., Tressaud A., Durand E. Electrochemical properties and structures of surface-fluorinated graphite for the lithium ion secondary battery // J. Fluorine Chem. 2002. — V. l 14. — P.209−214.
- Buqa H., Grogger Ch., Santis Alvarez M.V., Besenhard J.O., Winter M. Surface modification of graphite anodes by combination of high temperature gas treatment and silylation in nonaqueous solution // J. Power Sources. 2001. -V.97−98. — P.126−128.
- Kuribayashi I., Yakoyama M., Yamashita M. Battery characteristics with various carbonaceous materials // J. Power Sources. 1995. -V.54. — P. 1−5.
- Yoshio M., Wang H., Fukuda К., Hara Y., Adachi Y. Effect of carbon coating on electrochemical performance of treated natural graphite as lithium-ion battary anode material // J. Electrochem. Soc. 2000. — V.147. — P.1245−1250.
- Lee H.-Y., Baek J.-K., Jang S.-W., Lee S.-M. Hong S.-T., Lee K.-Y., Kim M.-H. Stress effect on cycle properties of the silicon thin-film anode // J. Power Sources. 2001. — V.97−98. — P.191−193.
- Simon В., Flandrois S., Fevrier-Bouvier A., Biensan P. // Mol. Cryst. Liq. Cryst. 1998. V. 310. P. 333. (цитируется no 21.)
- Cao F., Barsukov I., Bang H., Zaleski P., Prakash J. Evaluation of graphite materials as anodes for lithium-ion battaries // J. Electrochem. Soc. -2000.-V.147. P.3579−3583.
- Guerin K., Ferrier-Bouvier A., Flandrois S., Couzi M., Simon В., Biensan P. Effect of graphite crystal structure on lithium electrochemical intercalation // J. Electrochem. Soc. 1999. — V.146. — P.3660−3665
- Morita M., Ichimura Т., Ishikawa M., Matsuda Y. Effects of the Organic Solvent on the Electrochemical Lithium Intercalation Behavior of Graphite Electrode // J. Electrochemical Society. 1996. — V.143. — P.26−29.
- Yoshida H., Fukunaga Т., Hazama Т., Terasaki M., Mizutani M., Yamaji M.//Extended Abstracts, 36th Battary, Symposium, Kyoto, Japan. 1995. -paper № 1 BO 2.- P.101.
- Нижниковский E., Скундин А. Литиевые вторичные источники тока // Электронные компоненты. 2002. — № 7. — С. 117−118.
- Arora P., White R.E., Doyle М. Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries // J. Electrochem. Soc. 1998. — V.145. -P.3647−3668.
- Богданов А.А. Визуализация данных в Microcal Origin. M: «Альтекс-А», 2003. — 104c.
- Joho F., Rykart В., Blome A., Novak P., Wilhelm H., Spahr M.E. Relation between surface properties, pore structure and first-cycle charge loss of graphite as negative electrode in lithium-ion batteries // J. Power Sources. 2001. -V.97−98. — P.78−82.
- Hong Huang. Anode Materials for Lithium-ion Batteries.- Universal Press, Science Publishers, Veenendaal. 1999. — P. 151.
- Inagaki M., Iwashita N., Kouno E. Potential change with intercalation of sulfuric acid into graphite by chemical oxidation // Carbon. 1990. — V.28. -P.49−55.
- Фиалков A.C. Углерод, межслоевые соединения и композиты на его основе. М.: Аспект Пресс, 1997. — 339с.
- Jean М., Tranchant A., Messina R. Reactivity of Lithium Intercalated into Petroleum Coke with Carbonate Electrolytes // J. Electrochem. Soc. 1996. -V.143. — P.391−394.
- Egorkina O.Yu., Skundin A.M. The effect of temperature on lithium intercalation into carbon materials // J. Solid State Electrochem. 1998. — V.2.-P.216−220.1. Благодарности
- Выражаю огромную благодарность моему научному руководителю, НИКОЛАЮ ВАСИЛЬЕВИЧУ КОРОВИНУ, за предложенную тему диссертации и постоянную помощь при выполнении работы.
- Искренне благодарю Кулову Татьяну Львовну и Скундина Александра Матвеевича, сотрудников Института электрохимии им. А. Н. Фрумкина РАН, за неоценимую помощь, как в постановке экспериментов, так и в обсуждении результатов работы.