Межмолекулярные взаимодействия в системах, образованных полиядерными оксокарбоксилатными комплексами d-элементов
Диссертация
На основании результатов квантовохимических расчетов модельных дии тетрамерных объединений платины {цис-|ТЧ (ЫНз)2С12]}п (где п = 2 и 4) показано, что межмолекулярные невалентные силы сцепления вызывают понижение полных энергий олигомеров. Это позволяет сделать вывод о том, что термодинамическая устойчивость отдельных молекулярных блоков, образующих координационную надмолекулярную конструкцию… Читать ещё >
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