Синтез и изучение свойств мезо-арил-замещенных порфиринов для технологии Ленгмюра-Блоджетт

VI. ВЫВОДЫ.

1. Отработаны методы синтеза порфиринов, содержащих пентафторфенильные фрагменты.

2. Изучены свойства порфиринов, содержащих пентафторфенильные фрагменты, в пленках Ленгмюра-Блоджетт.

3 Получены данные об уникальном автост^ктущшовании 10. 15- 20* * «J I ^ Г» Г* У У 7 тетракис (пентафторфенил)порфирина в пленках Ленгмюра-Блоджетт, в том числе методом сканирующей туннельной микроскопии, и показано влияние пентафторфенильных заместителей на структуру пленки.

4. Изучено поведение 5, 10, 15, 20-тетракис (3,5-ди-тре/и.-бутил-4-гидрокси-фенил)порфирина в растворах и пленках Ленгмюра-Блоджетт.

5. Синтезирован ряд хинонсодержащих порфиринов, обладающих пониженной склонностью к агрегации и пригодных для моделирования процессов переноса электронов.

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120. Автор выражает искреннюю благодарность и признательность за проявленный интерес и помощь в работе профессору Хельге Лемметюйнену, к.ф.-м.н. Ткаченко Н. В., к.х.н. Аникину М. В., к.х.н. Румянцевой В. Д., к.х.н. Грибкову A.A., к.х.н.1. Тауберу А.Ю.