Спектроскопия ЭПР радикальных производных фуллеренов изолированных в твердой матрице аргона
Диссертация
Показано, что в эндометаллофуллеренов Sc@Cg2 конфигурация спиновой плотности на атоме металла отвечает заселенной dyz электронной орбитали, в отличие от тяжелых атомов иттрия (У@С82) и лантана (La@C82), у которых конфигурация спиновой плотности соответствует гибридизованной орбитали, образованной взаимодействием электронных dyzи руорбиталей атома металла с атомами углерода на фуллереновой сфере… Читать ещё >
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