Физико-химическое моделирование поведения тяжелых металлов (Cu, Zn, Cd) в природных водах: Комплексы в растворе, адсорбция, ионный обмен, транспортные явления
Диссертация
Краткая аннотация. Работа посвящена численному моделированию поведения тяжелых металлов (Си, Zn, Cd) в природных водах. В основном тексте дано описание химических моделей (вместе с базами данных): равновесий макрокомпонентов (Н+, Na+, К, Са, Mg, СГ, SO4 СОз ') и тяжелых металлов в природных (пресных — морских) водахвзаимодействия тяжелых металлов с органическим веществом, твердым… Читать ещё >
Список литературы
- Браунлоу А. X. (1984) Геохимия. Пер. с англ. М.: «Недра».
- Брунауэр С. (1948) Адсорбция газов и паров. Пер. с англ. М.: ИЛ.
- Гаррелс, P.M., и Крайст, Ч.Л. (1968) Растворы, минералы, равновесия. М., «Мир».
- Дривер Дж. (1985) Геохимия природных вод. Пер. с англ., М.: «Мир».
- Кеннетт, Дж.П. (1987) Морская геология. М.: «Мир».
- Колемаев В.А., Староверов, О.В., Турундаевский, В.Б. (1991) Теория вероятностей и математическая статистика. М: «Высш. шк.».
- Костов И. (1971) Минералогия. М.: «Мир».
- Краткий справочник физико-химических величин. Изд 8-е, перераб. (Под ред. Равделя А. А и Пономаревой A.M.) Л.: «Химия», 1983.
- Кульчитский Л. И. и Урусьянов О. Г. (1981) Физико-химические основы формирования свойств глинистых пород. М.: «Недра».
- Пивоваров С.А. (2001) Влияние структуры поверхности на адсорбцию ионов. Тезисы XIV российского совещания по экспериментальной минералогии. Черноголовка. Стр. 305.
- Пивоваров, С.А., Лакштанов, Л.З. (2002) Адсорбция кадмия на гематите. Геохимия.1. В печ.
- Пивоваров С.А. (2002) Сорбция ионов (Cu2+, Zn2+, Cd2+, Са2+, Na+, СГ, S042', С032″) на (гидр)оксидах трехвалентного железа. В сб.: Экспериментальное и теоретическое моделирование процессов минералообразования. В печ.
- Урусов, B.C., Таусон, В.Л., Акимов, В.В. (1997) Геохимия твердого тела. М.: «ГЕОС».
- Ali, М. А. (1994) The influence of simple organic acids on sorption of inorganic ions at the goethite/water interface. Ph. D. thesis. Carnegie Mellon University. Pittsburgh, USA.
- Baes, Ch.F.Jr., Mesmer, R.E. (1976) The Hydrolysis of Cations. John Wiley & Sons, Inc.: New York.
- Balistriery L. S., and Murray J. W. (1982) The adsorption of Cu, Pb, Zn, and Cd on goethite from major ion seawater. Geochimica Cosmochimica Acta 46,1253−1265.
- Benjamin M. M., and Leckie J. O. (1981) Multiple-site adsorption of Cd, Cu, Zn, and Pb on amorphous iron oxyhydroxide. J. Colloid Interface Sci. 79, 209−221.
- Bousse L., De Rooij N. F., Bergveld P. (1983) The influence of counter-ion adsorption on the Уо/рН characteristics of insulator surfaces. Surf. Sci., 135, 479−486.
- Bowden J. W., Nagarajah S., Barrow N. J., Posner A. M., and Quirk P. J. (1980) Describing the adsorption of phosphate, citrate and selenite on variable-charge mineral surface. Aust. J. Soil. Res. 18,49−60.
- Brady P. V., Cygan R. Т., and Nagy K. L. (1996) Molecular control on kaolinite surface charge. J. Colloid Interface Sci. 183,356−364.
- Byrne, R.H., Miller, W.L. (1985) Copper (II) carbonate complexation in seawater. Geochim. Cosmochim. Acta 49, 1837−1844.
- Cabaniss S.E., and Shuman M.S. (1988) Copper binding by dissolved organic matter: I. Suwannee river fulvic acid equilibria. Geochim. Cosmochim. Acta 52,185−193.
- Cauwet, G., and Sidorov, I. (1996) The biochemistry of Lena river: organic carbon and nutrients distribution. Mar. Chem. 53,211−227.
- Chao, T.T., and Zhou, L. (1983) Extraction techniques for selective dissolution of amorphous iron oxides from soils and sediments. Soil Sci. Soc. Amer. J. 47,225−232.
- Chapman D. L. (1913) A contribution to the theory of electrocapillarity. Philos. Mag. 6(25), 475−481.
- Gouy G. (1910) Sur la constitution de la charge electrique a la surface d’un electrolyte. J. Phys. 9,457−468.
- Grahame D. C. (1947) The electrical double layer and the theory of electrocapillarity. Chem. Rev. 41, 441−501.
- Christensen, Т.Н., Lehmann, N., Jackson, Т., Holm, P.E. (1996) Cadmium and nickel distribution coefficients for sandy aquifer materials. J. Contaminant Hydrol. 24, 75−84.ф"
- Christensen, Т.Н., Astrup, Т., Boddum, J.K., Hansen, В. 0., Redemann, S. (2000) Copper and zink distribution coefficients for sandy aquifer materials. Wat. Res. 34,709−712.
- Christl, I., and Kretzschmar, R. (1999) Competitive sorption of copper and lead at the oxide-water interface: implication for surface site density. Geochim. Cosmochim. Acta 63, 29 292 938.
- Comans, R.N.J., Middelburg, J.J. (1987) Sorption of trace metals on calcite: applicability of the surface precipitation model. Geochim. Cosmochim. Acta 51,2587−2591.
- Coston, J. A., Fuller, C.C., Davis, J. A. (1995) Pb2+ and Zn2+ adsorption by a natural aluminum- and iron-bearing surface coating on an aquifer sand. Geochim. Cosmochim. Acta 59, 3535−3547.
- Cornell, R.M., and Schwertmann, U. (1996) The iron oxides. Structure, properties, reactions, occurence and uses. VCH: New York.
- Cowan С. E., Zachara J. M., Smith S. C. and Resch С. T. (1992) Individual sorbent contributions to cadmium sorption on ultisols of mixed mineralogy. Soil Sci. Soc. Am. J. 56, 1084−1094.
- Davies-Colley R. J., Nelson P. O., and Williamson K. J. (1984) Copper and cadmium Ф uptake by estuarine sedimentary phases. Environ. Sci. Technol. 18,491−499.
- Davis, J. A. (1977) Adsorption of trace metals and complexing ligands at the oxide/water interface. Ph.D. thesis: Stanford University.
- Davis J. A., and Leckie J. O. (1978) Effect of adsorbed complexing ligands on trace metal uptake by hydrous oxides. Environ. Sci. Technol. 12, 1309−1315.
- Davis J. A., James R. O., and Leckie J. O. (1978) Surface ionization and complexation at oxide/water interface. I. Computation of electrical double layer properties in simple electrolytes. J. Colloid Interface Sci. 63,480−499.
- Davis, J.A., Coston, J.A., Kent, D.B., and Fuller, C.C. (1998) Application of the surface complexation concept to complex mineral assemblages. Environ. Sci. Technol. 32,2820−2828.
- Delay, F., Porel, G., Marsily, G. (1997) Predicting solute transport in heterogeneous media from results obtained in homogeneous ones: an experimental approach. J. Contaminant Hydrol. 25, 63−84.
- Dickson, A.G., and Millero, F.J. (1987) A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media. Deep-Sea Res. 34, 1733−1743.
- Dzombak D. A., and Morel F. M. M. (1990) Surface complexation modeling. Hydrous ferric oxide. John Wiley & Sons, Inc.: New York.
- Ephraim, J.H. (1992) Heterogeneity as a concept in the interpretation of metal ion binding by humic substances. The binding of zinc by an aquatic fulvic acid. Analytica Chim. Acta 267, 39−45.
- Fletcher, P., and Sposito, G. (1989) The chemical modeling of clay/electrolyte interactions for montmorillonite. Clay Miner. 24, 375−391.
- Gabriel, U., Gaudet, J.P., Spadini, L., and Charlet, L. (1998) Reactive transport of uranil in a goethite column: an experimental and modelling study. Chemical Geology 151, 107−128.
- Gaillardet, J., Dupre, В., and Allegre, C.J. (1999) Geochemistry of large river suspended sediments: silicate weathering or recycling tracer? Geochim. Cosmochim. Acta 63,4037−4051.
- Gamier, J.-M., Martin, J.-M., Mouchel., J.-M., and Siod, K. (1996) Partitioning of trace metals between the dissolved and particulate phases and particulate surface reactivity in the Lena river estuary and the Laptev Sea (Russia). Mar. Chem. 53,269−283.
- Gordeev, Y.Y., and Sidorov, I.S. (1993) Concentrations of major elements and their outflow into the Laptev sea by Lena river. Mar. Chem. 43, 33−45.
- Gouy G. (1910) Sur la constitution de la charge electrique a la surface d’un electrolyte. J. Phys. 9, 457−468.
- Grahame D. C. (1947) The electrical double layer and the theory of electrocapillarity. Chem. Rev. 41, 441−501.
- Guieu, C., Huang, W.W., Martin, J.-M., Yong, Y.Y. (1996) Outflow of trace metals into the Laptev sea by Lena river. Mar. Chem. 53,255−267.
- Gunneriusson L. (1994) Composition and stability of Cd(II)-chloro and -hydroxo complexes at goethite (a-FeOOH)/water interface. J. Colloid Interface Sci. 163,484−492.
- Harsh, J.B., Doner, H.E., and McBride, M.B. (1984) Chemisorption of copper on hydroxy-aluminum-hectorite: An electron spin resonance study. Clays Clay Miner. 32, 407−413.
- Hayes, K.F. (1987) Equilibrium, spectroscopic, and kinetic studies of ion adsorption at the oxide/aqueous interface. Ph.D. thesis, Stanford University, Stanford, USA.
- Hayes K. F., and Leckie J. O. (1987) Modeling ionic strength effects on cation adsorption at hydrous oxide/solution interface. J. Colloid Interface Sci. 115, 564−572.
- Hohl, H., and Stumm, W. (1976) Interaction of Pb2+ with hydrous a-Al203. J. Colloid Interface Sci. 55,281−288.
- Hsi Ch-K. D., Langmuir D. (1985) Adsorption of uranyl onto ferric oxyhydroxides: application of the surface complexation site-binding model. Geochim. Cosmochim. Acta 49, 1931−1941.
- Jean, G.E., Bancroft, G.M. (1986) Heavy metal adsorption by sulphide mineral surfaces. Geochim. Cosmochim. Acta 50, 1455−1463.
- Kornicker, W.A., Morse, J.W. (1991) Interaction of divalent cations with the surface of pyrite. Geochim. Cosmochim. Acta 55, 2159−2171.
- Machesky, M.L., Wesolowski D.J., Palmer, D.A., and Ichiro-Hayashi, K. (1998) Potentiometric titrations of rutile suspensions to 250 °C. J. Colloid Interface Sci. 200, 298−309.
- Meybeck, M. (1979) Concentrations des eaux fluviales en elements majeurs et apports en solution aux oceans. Rev. Geogr. Phys. Geol. Dyn. 21,215−246.
- Millero, F.J., and Pierrot, D. (1998) A chemical equilibrium model for natural waters. Aquatic Geochem. 4, 153−199.
- Nolting, R.F., van Dalen, M., and Helder, W. (1996) Distribution of trace and major elements in sediment and pore waters of the Lena delta and Laptev sea. Mar. Chem. 53,285−299.
- Oakley, S.M., Nelson, P.O., Williamson, K.J. (1981) Model of trace-metal partitioning in marine sediments. Environ. Sci. Technol. 15,474−480.
- Parks G. A., and de Bruyn P. L. (1962) The zero point of charge of oxides. J. Phys. Chem. 66, 967−973.
- Persson P., and L6vgren L. (1996) Potentiometric and spectroscopic studies of sulfate complexation at the goethite-water interface. Geochim. et Cosmochim. Acta 60, 2789−2799.
- Pivovarov S. (1997) Acid-base properties of hematite at elevated temperatures. In: Oric. 5th Int. Symp. on Hydrothermal Reactions, Gatlinburg, USA, 295−296.
- Pivovarov S. (1997) Surface structure and site density of oxide-solution interface. J. Colloid Interface Sci. 196, 321−323.
- Pivovarov S. (1998) Acid-base properties and heavy and alkaline earth metal adsorption on the oxide-solution interface: non-electrostatic model. J. Colloid Interface Sci. 206, 122−130.
- Pivovarov S.A., Alyokhin Yu.V. (1998) Calculation of the thermodynamic constants of polymerization for water vapor molecules. Experiment in Geosciences 5, № 2,22−23.
- Pivovarov S.A. (1998) Adsorption of ions on the hematite surface. Experiment in Geosciences 6, № 2,34−35.
- Pivovarov S.A., Lakshtanov L.Z. (1999) Sorption of cadmium on hematite in a wide range of sorbate/sorbent ratios. Experiment in Geosciences 7, № 1,50−51.
- Pivovarov S.A. (2000) Cadmium adsorption on ferric iron oxide. Experiment in Geosciences 8, № 1, 71−72.
- Pivovarov S. (2000) Theoretical structures of mineral-solution interfaces. In: Surface Chemical Processes in Natural Environments. Monte Verita, Ascona, Switzerland, p. 46.
- Pivovarov S. (2001) Adsorption of cadmium onto hematite: temperature dependence. J. Colloid Interface Sci. 234,1−8.
- Pivovarov, S. (2002) Structure of the oxide-solution interface. In: Encyclopedia of Surface and Colloid Science (Eds. A. Hubbard, P. Somasundaran). Marcel Dekker, Inc.: New York, pp. 4869−4877.
- Pivovarov, S. (2003) Physico-chemical modeling of heavy metals (zinc, cadmium, copper) in natural environments. In: Encyclopedia of Surface and Colloid Science
- Eds. A. Hubbard, P. Somasundaran). Marcel Dekker, Inc.: New York (electronic updates: http://www.dekker.com/servlet/product/productid/E-ESCS).
- Pokrovsky, O.S., Schott, J., and Thomas, F. (1999) Processes at the magnesium-bearing carbonates/solution interface. I. A surface speciation model for magnesite. Geochim. Cosmochim. Acta 63, 863−880.
- Ravat, C., Dumonceau, J., Monteil-Rivera, F. (2000a) Acid/base and Cu (II) binding properties of natural organic matter extracted from wheat bran: modeling by the surface complexation model. Wat. Res. 34, 1327−1339.
- Ravat, C., Monteil-Rivera, F., Dumonceau, J. (2000b) Metal ions binding to natural organic matter extracted from wheat bran: application of the surface complexation model. J. Colloid Interface Sci. 225, 329−339.
- Schindler, P.W., and Kamber, H.R. (1968) Die acitat von silanolgruppen. Helv. Chim. Acta 51, 1781−1786.
- Schindler, P. W., Liechti, P., Westall, J.C. (1987) Adsorption of copper, cadmium and lead from aqueous solutions to the kaolinite/water interface. Neth. J. Agric. Sci. 35,219−230.
- Schindler, P., Reinert, M., Gamsjager, H. (1969) Zur Thermodynamik der Metallcarbonate 3. Loslichkeitskonstanten und Freie Bildungsenthalpien von ZnCC>3 und Zn5(0H)6(C03)2 bei 25 °C. Helv. Chim. Acta 52,2327−2337.
- Sigg, L., Sturm, M., Kistler, D. (1987) Vertical transport of heavy metals by settling particles in lake Zurich. Limnol. Oceanogr. 32(1), 112−130.
- Sigg, L., Kistler, D., and Ulrich, M.M. (1996) Seasonal variations of zinc in a eutrophic lake. Aquatic Geochem. 1, 313−328.
- Sposito, G., Holtzclaw, K.M., Charlet, L., Jouany, C., and Page, A.L. (1983) Sodium-calcium and sodium-magnesium exchange on Wyoming bentonite in perchlorate and chloride background ionic media. Soil Sci. Soc. Am. J. 47, 51−56.
- Sposito, G., and LeVesque, C.S. (1985) Sodium-calcium-magnesium exchange on Silver Hill illite. Soil Sci. Soc. Am. J. 49,1153−1159.
- Stern O. (1924) Zur theory der electrolytischen doppelschicht. Z. Electrochem. 30, 508 516.
- Stumm, W. (1992) Chemistry of the solid-water interface. John Wiley & Sons, Inc.: New1. York.
- Stumm, W., Huang, C.P., and Jenkins, S.R. (1970) Specific chemical interactions affecting the stability of dispersed systems. Croat. Chem. Acta 42, 223−244.
- Stumm, W., and Morgan, J.J. (1970) Aquatic Chemistry. John Wiley & Sons, Inc.: New1. York.
- Tamm, O. (1922) Eine Methode zur Bestimmung der anorganischen Komponenten des Gelkomplexes im Boden. Medd. Statens skogsforsoksanstalt 19,385−404.
- Tamm, O. (1932) Uber die Oxalatmethode in der chemischen Bodenanalyse. Medd. Statens skogsforsoksanstalt 27, 1−20.
- Taylor, S.R., and McLennan, S.M. (1985) The Continental Crust: its Composition and Evolution. Blackwell: London.
- Tejedor-Tejedor M. I., and Anderson M. A. (1990) Protonation of phosphate on the surface of goethite as studied by CIR-FTIR and electrophoretic mobility. Langmuir 6, 602−612.
- Tipping E. (1998), Humic ion-binding model VI: an improved description of the interactions of protons and metal ions with humic substances. Aquatic Geochem. 4, 3−48.
- Tipping E., and Hurley M. A (1992). A unifying model of cation binding by humic substances. Geochim. Cosmochim. Acta 56,3627−3641.
- Turner, D.R., Whitfield, M., Dickson, A.G. (1981) The equilibrium speciation of dissolved components in freshwater and seawater at 25 °C and 1 atm pressure. Geochim. Cosmochim. Acta 45, 855−881.
- Van der Weijden, R.D., van der Weijden, C.H., and Comans, R.N.J. (1994) Sorption and sorption reversibility of Cd on calcite under simulated riverine, estuarine and marine conditions. Mar. Chem. 47, 65−79.
- Van Riemsdijk W. H., Bolt G. H., Koopal L. K., and Blaakmeer, J. (1986) Electrolyte adsorption on heterogeneous surfaces: adsorption models. J. Colloid Interface Sci. 109, 219−228.
- Venema, P., Hiemstra, Т., Weidler, P.G., and Van Riemsdijk, W.H. (1998) Intrinsic proton affinity of reactive surface groups of metal (hydr)oxides: application to iron (hydr)oxides. J. Colloid. Interface Sci. 198,282−295.
- Villalobos, M., and Leckie, J.O. (2000) Carbonate adsorption on goethite under closed and open CO2 conditions. Geochim. Cosmochim. Acta 64, 3787−3802.
- Wang F., Chen J., and Forsling W. (1997) Modeling sorption of trace metals on natural sediments by surface complexation model. Environ. Sci. Technol. 31,448−453.
- Whitfield, M., and Turner, D.R. (1987) The role of particles in the composition of seawater. In: Aquatic surface Chemistry (Ed. Stumm, W.) pp. 457−493, John Wiley & Sons, Inc.: New York.
- Zachara J. M., Cowan С. E., Resch С. T. (1991) Sorption of divalent metals on calcite. Geochim. Cosmochim. Acta 55, 1549−1562.
- Zachara J. M., Smith S. C., Resch С. Т., and Cowan С. E. (1992) Cadmium sorption to soil separates containing layer silicates and iron and aluminium oxides. Soil Sci. Soc. Am. J. 56, 1074−1084.
- Zhang Z. Z., and Sparks D. L. (1996) Sodium-copper exchange on Wyoming montmorillonite in chloride, perchloride, nitrate, and sulfate solutions. Soil Sci. Soc. Am. J. 60, 1750−1757.